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臭氧濃度與安全

作者:上海峰志 時(shí)間:2022-08-24 22:00:20瀏覽867 次

信息摘要:

Ozone is a gaseous substance with a strong oxidizing power that gives us good effects. However, as ozone is harmful to living organisms on the other hand, we have to understand well the relation of ozone gas concentration with effect and harm so that we can make the most of its effects in compliance with safety requirements. T

Relation of Ozone Concentration with Safety and Effects

Ozone is a gaseous substance with a strong oxidizing power that gives us good effects. However, as ozone is harmful to living organisms on the other hand, we have to understand well the relation of ozone gas concentration with effect and harm so that we can make the most of its effects in compliance with safety requirements. To this end it is essential for us to make accurate management of the concentration of ozone. Shown in Table 1 is part of the relation between the concentration and beneficial effect or harm. A guideline as to the safety standard of ozone in a work environment is laid down by the Society for Occupational Health and Permissible Concentration Committee.

Table 1. Ozone Concentration and Its Characteristics

Concentration
       (ppm)
Characteristics (Effect and Harm)
0.02-0.05No ozone odor is felt below this range although there are great differences among individuals. As the permissible value is 0.1ppm at present, no odor ensures an absolute safety. So, the human sense of odor makes an excellent and most inexpensive monitor.
0.05-0.1Permissible value for eight-hour labor (40 hours per week).
       Ozone odor is felt.
0.3Permissible value when exposed for a short time of 15 minutes or less.
0.5In case a healthy person does a contingent work for a short time (within one hour), there is no worry with less than this concentration. However, ozone irritates nose and throat. Too much irritation may cause headache, chest pain, respiratory thirst or coughing. You are suggested to wear a mask with activated carbon.
0.5-1.0With more concentration than this level and long operation of one week or longer, ozone sterilizes inside of the room, deodorizes and gives a cockroach repelling effect2?.
10In some dozens of minutes you may become unable to breathe, suffer pulmonary edema and go into a coma.
40Sterilizing effect equivalent to formalin gas, used for disinfection of aseptic hospital wards3?

1) American Conference of Governmental Industrial Hygienist; Ozone, Documentation Review/revised, 453, 1987, CAS; 10028-15-6”
 2) Published Unexamined Application № . 62-215509, Title : Cockroach Repelling Method applied by Shigeo Ohki
3) Toru Masaoka, “Aseptic patient room in Osaka Medical Center for Cancer and Cardiovascular Diseases” Lifestyle-related diseases, 20(1), 15-21, 1979

They adopted the values from those laid down by the American Conference of Governmental Industrial Hygienists. They regulated the permissible concentration of ozone at 0.05~0.1ppm for eight working hours per day, 40 hours per week, and at 0.3ppm for an exposure of 15 minutes or shorter. 1?

You can measure an ozone concentration within the range related to safety management in use of an inexpensive densitometer of gas detection type which is available at 10,000 yen or a little more in the market.

breathing-in-ozone-generated-by-ozone-machines.jpg

臭氧安全濃度是多少?

根據(jù)清華大學(xué)編的《臭氧技術(shù)應(yīng)用文集》一書,將有關(guān)臭氧應(yīng)用濃度按安全濃度空氣、應(yīng)用濃度、水中應(yīng)用濃度、環(huán)境濃度及感知濃度,分類摘錄,以便在應(yīng)用中查找。 安全濃度人們?cè)试S接觸的臭氧濃度不大于0.2mg/m3。

臭氧工業(yè)衛(wèi)生標(biāo)準(zhǔn): 臭氧協(xié)會(huì): 0.1 ppm,接觸10小時(shí) 美 國: 0.1 ppm,接觸 8小時(shí) 德、法、日 本: 0.1 ppm中 國: 0.15ppm

家用臭氧柜外臭氧泄漏量不得超過0.2mg/m3(指1.5米以外),一個(gè)周期后殘留濃度不得大于0.2mg/m?。

動(dòng)物試驗(yàn)表明,臭氧毒性的起點(diǎn)濃度為0.3ppm,而人對(duì)空氣中臭氧可嗅知的濃度為0.02~0.04ppm,根據(jù)臭氧對(duì)肺功能毒性的試驗(yàn)結(jié)果,提出1.5~2.0ppm為臭氧允許濃度的上限。衛(wèi)生部規(guī)定臭氧高允許濃度為0.2mg/m?。


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